|
Solution analyses for strontium sorption to goethite in air, I = 0.1 M NaNO3 and T = 25°C. |
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| Final pH |
Surface Area m2 L-1 |
Initial [Sr] M |
Final [Sr] M |
%Sr sorbed |
Γ Sr sorbed Mol m-2 |
Total Dissolved Carbonate M |
|
|
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| Total Sr = 10-4M aged for 2 days |
± 5% |
|||||
|
|
||||||
| 3.98 |
266 |
9.61 × 10-5 |
9.44 × 10-5 |
1.8 |
6.60 × 10-9 |
not measured |
| 4.89 |
271 |
9.79 × 10-5 |
9.79 × 10-5 |
0.1 |
2.00 × 10-10 |
not measured |
| 6.11 |
269 |
9.74 × 10-5 |
9.59 × 10-5 |
1.5 |
5.33 × 10-9 |
not measured |
| 7.13 |
265 |
9.58 × 10-5 |
1.01 × 10-4 |
-5.1 |
-1.86 × 10-8 |
not measured |
| 7.95 |
264 |
9.55 × 10-5 |
9.11 × 10-5 |
4.6 |
1.67 × 10-8 |
not measured |
| 8.85 |
263 |
9.50 × 10-5 |
7.97 × 10-5 |
16.1 |
5.82 × 10-8 |
not measured |
| 9.91 |
261 |
9.44 × 10-5 |
4.61 × 10-5 |
51.2 |
1.85 × 10-7 |
not measured |
|
|
||||||
| Total Sr = 10-5 M aged for 2 days |
± 5% |
|||||
|
|
||||||
| 3.99 |
275 |
1.01 × 10-5 |
9.86 × 10-6 |
2.0 |
7.19 × 10-10 |
not measured |
| 5.09 |
275 |
1.00 × 10-5 |
1.02 × 10-5 |
-2.2 |
-8.14 × 10-10 |
not measured |
| 6.22 |
274 |
1.00 × 10-5 |
1.01 × 10-5 |
-0.8 |
-2.76 × 10-10 |
not measured |
| 7.29 |
273 |
9.99 × 10-6 |
9.35 × 10-6 |
6.4 |
2.34 × 10-9 |
not measured |
| 8.15 |
277 |
1.01 × 10-5 |
7.26 × 10-6 |
28.2 |
1.03 × 10-8 |
not measured |
| 8.92 |
275 |
1.01 × 10-5 |
4.54 × 10-6 |
54.8 |
2.00 × 10-8 |
not measured |
| 9.95 |
271 |
9.91 × 10-6 |
1.60 × 10-6 |
83.9 |
3.06 × 10-8 |
not measured |
|
|
||||||
| Total Sr = 1.1 × 10-6 M aged for 2 days |
(± 7%) |
|||||
|
|
||||||
| 4.04 |
273 |
1.10 × 10-6 |
9.82 × 10-7 |
10.4 |
4.17 × 10-10 |
not measured |
| 4.97 |
274 |
1.10 × 10-6 |
9.93 × 10-7 |
9.6 |
3.83 × 10-10 |
not measured |
| 6.11 |
273 |
1.09 × 10-6 |
1.02 × 10-6 |
7.1 |
2.84 × 10-10 |
not measured |
| 7.22 |
275 |
1.10 × 10-6 |
1.04 × 10-6 |
5.6 |
2.25 × 10-10 |
not measured |
| 7.95 |
271 |
1.09 × 10-6 |
9.59 × 10-7 |
11.8 |
4.73 × 10-10 |
not measured |
| 8.95 |
273 |
1.09 × 10-6 |
5.14 × 10-7 |
53.0 |
2.13 × 10-9 |
not measured |
| 9.94 |
270 |
1.08 × 10-6 |
1.14 × 10-7 |
89.5 |
3.59 × 10-9 |
not measured |
Carroll et al. Geochemical Transactions 2008 9:2 doi:10.1186/1467-4866-9-2 |
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