|
Solution analyses for strontium sorption to goethite in air, I = 0.1 M NaCl and T = 25°C. |
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| Final pH |
Surface Area m2 L-1 |
Initial [Sr] M |
Final [Sr] M |
%Sr sorbed |
Γ Sr sorbed Mol m-2 |
Total Dissolved Carbonate M |
|
|
||||||
| Total Sr = 10-4 M aged for 2 days |
± 5% |
|||||
|
|
||||||
| 6.43 |
1299 |
1.10 × 10-4 |
1.06 × 10-4 |
3.9 |
3.34 × 10-9 |
not measured |
| 6.85 |
1304 |
1.10 × 10-4 |
1.07 × 10-4 |
2.5 |
2.13 × 10-9 |
not measured |
| 7.23 |
1307 |
1.10 × 10-4 |
1.08 × 10-4 |
1.8 |
1.49 × 10-9 |
not measured |
| 7.62 |
1311 |
1.11 × 10-4 |
1.02 × 10-4 |
8.4 |
7.13 × 10-9 |
not measured |
| 7.97 |
1309 |
1.11 × 10-4 |
1.03 × 10-4 |
6.8 |
5.71 × 10-9 |
not measured |
| 8.29 |
1305 |
1.1 × 10-4 |
1.17 × 10-4 |
-5.8 |
-4.92 × 10-9 |
not measured |
| 8.96 |
1304 |
1.10 × 10-4 |
6.18 × 10-4 |
43.7 |
3.68 × 10-8 |
not measured |
| 9.28 |
1297 |
1.09 × 10-4 |
4.11 × 10-4 |
62.4 |
5.26 × 10-8 |
not measured |
| 9.97 |
1278 |
1.08 × 10-4 |
2.30 × 10-5 |
78.8 |
6.68 × 10-8 |
not measured |
|
|
||||||
| Total Sr = 10-4 M aged for 14 days |
± 5% |
|||||
|
|
||||||
| 6.52 |
1478 |
1.11 × 10-4 |
1.09 × 10-4 |
1.9 |
1.43 × 10-9 |
1.47 × 10-4 |
| 7.03 |
1513 |
1.11 × 10-4 |
1.06 × 10-4 |
5.0 |
3.69 × 10-9 |
2.10 × 10-4 |
| 7.50 |
1523 |
1.12 × 10-4 |
1.01 × 10-4 |
9.5 |
6.97 × 10-9 |
3.76 × 10-4 |
| 8.12 |
1491 |
1.11 × 10-4 |
8.20 × 10-5 |
26.4 |
1.97 × 10-8 |
5.29 × 10-4 |
| 8.18 |
1507 |
1.11 × 10-4 |
6.84 × 10-5 |
38.4 |
2.83 × 10-8 |
6.38 × 10-4 |
| 9.19 |
1478 |
1.11 × 10-4 |
4.20 × 10-5 |
62.0 |
4.64 × 10-8 |
7.22 × 10-4 |
| 9.84 |
1484 |
1.10 × 10-4 |
2.17 × 10-5 |
80.2 |
5.93 × 10-8 |
8.93 × 10-4 |
| 10.59 |
1453 |
1.09 × 10-4 |
7.54 × 10-6 |
93.1 |
6.96 × 10-8 |
9.97 × 10-4 |
| 11.32 |
1416 |
1.06 × 10-4 |
2.15 × 10-6 |
98.0 |
7.34 × 10-8 |
1.07 × 10-3 |
|
|
||||||
| Total Sr = 10-5 M aged for 2 days |
± 5% |
|||||
|
|
||||||
| 6.89 |
1301 |
1.17 × 10-5 |
9.81 × 10-6 |
16.4 |
1.48 × 10-9 |
not measured |
| 7.18 |
1310 |
1.18 × 10-5 |
1.00 × 10-5 |
15.0 |
1.35 × 10-9 |
not measured |
| 7.51 |
1309 |
1.18 × 10-5 |
9.49 × 10-6 |
19.6 |
1.77 × 10-9 |
not measured |
| 7.86 |
1308 |
1.18 × 10-5 |
8.64 × 10-6 |
26.7 |
2.41 × 10-9 |
not measured |
| 8.18 |
1304 |
1.18 × 10-5 |
7.36 × 10-6 |
37.4 |
3.37 × 10-9 |
not measured |
| 8.76 |
1300 |
1.17 × 10-5 |
4.51 × 10-6 |
61.4 |
5.52 × 10-9 |
not measured |
| 9.44 |
1293 |
1.16 × 10-5 |
3.45 × 10-6 |
70.4 |
6.34 × 10-9 |
not measured |
| 10.05 |
1285 |
1.15 × 10-5 |
7.57 × 10-7 |
93.4 |
8.40 × 10-9 |
not measured |
|
|
||||||
| Total Sr = 10-5 M aged for 14 days |
± 5% |
|||||
|
|
||||||
| 6.60 |
1484 |
1.30 × 10-5 |
1.25 × 10-5 |
3.1 |
2.74 × 10-10 |
1.04 × 10-4 |
| 7.17 |
1482 |
1.30 × 10-5 |
1.27 × 10-5 |
2.4 |
2.09 × 10-10 |
2.08 × 10-4 |
| 8.36 |
1441 |
1.30 × 10-5 |
7.73 × 10-6 |
40.6 |
3.66 × 10-9 |
5.83 × 10-4 |
| 9.36 |
1488 |
1.29 × 10-5 |
2.06 × 10-6 |
84.1 |
7.30 × 10-9 |
8.14 × 10-4 |
| 9.92 |
1491 |
1.28 × 10-5 |
6.79 × 10-7 |
94.7 |
8.15 × 10-9 |
9.33 × 10-4 |
| 10.55 |
1485 |
1.27 × 10-5 |
1.33 × 10-7 |
99.0 |
8.46 × 10-9 |
1.08 × 10-3 |
|
|
||||||
| Total Sr = 1.3 × 10-6 M aged for 2 days |
(± 12%) |
|||||
|
|
||||||
| 6.28 |
1296 |
1.28 × 10-6 |
1.19 × 10-6 |
7.1 |
7.03E × 10-11 |
not measured |
| 6.58 |
1302 |
1.29 × 10-6 |
1.31 × 10-6 |
-1.5 |
-1.50 × 10-11 |
not measured |
| 7.08 |
1306 |
1.29 × 10-6 |
1.11 × 10-6 |
14.1 |
1.39 × 10-10 |
not measured |
| 7.38 |
1131 |
1.27 × 10-6 |
1.11 × 10-6 |
12.6 |
1.41 × 10-10 |
not measured |
| 7.65 |
1090 |
1.26 × 10-6 |
9.95 × 10-7 |
21.1 |
2.43 × 10-10 |
not measured |
| 8.09 |
1057 |
1.25 × 10-6 |
7.21 × 10-7 |
42.4 |
5.02 × 10-10 |
not measured |
| 8.78 |
1055 |
1.25 × 10-6 |
3.55 × 10-7 |
71.5 |
8.45 × 10-10 |
not measured |
| 9.49 |
970 |
1.23 × 10-6 |
1.26 × 10-7 |
89.8 |
1.14 × 10-9 |
not measured |
| 10.05 |
884 |
1.21 × 10-6 |
3.44 × 10-8 |
97.2 |
1.33 × 10-9 |
not measured |
Carroll et al. Geochemical Transactions 2008 9:2 doi:10.1186/1467-4866-9-2 |
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