|
Solution analyses for strontium sorption to goethite in nitrogen atmosphere, I = 0.1 M NaCl and T = 25°C. |
|||||
| Final pH |
Surface Area m2 L-1 |
Initial [Sr] M |
Final [Sr] M |
%Sr sorbed |
Γ Sr sorbed Mol m-2 |
|
|
|||||
| Total Sr = 10-3 M, aged for 2 days |
± 5% |
||||
|
|
|||||
| 6.53 |
1412 |
9.20 × 10-4 |
9.44 × 10-4 |
-2.5 |
-1.65 × 10-8 |
| 6.79 |
1435 |
9.25 × 10-4 |
9.26 × 10-4 |
-0.2 |
-1.01 × 10-9 |
| 6.96 |
1457 |
9.26 × 10-4 |
9.06 × 10-4 |
2.2 |
1.37 × 10-8 |
| 7.26 |
1565 |
9.30 × 10-4 |
8.47 × 10-4 |
8.9 |
5.30 × 10-8 |
| 7.40 |
1449 |
9.27 × 10-4 |
8.07 × 10-4 |
12.9 |
8.28 × 10-8 |
| 7.82 |
1433 |
9.23 × 10-4 |
6.85 × 10-4 |
25.8 |
1.66 × 10-7 |
| 8.30 |
1478 |
9.20 × 10-4 |
6.23 × 10-4 |
32.3 |
2.01 × 10-7 |
| 8.91 |
1479 |
9.16 × 10-4 |
5.27 × 10-4 |
42.5 |
2.63 × 10-7 |
| 9.49 |
1445 |
9.12 × 10-4 |
3.28 × 10-4 |
64.0 |
4.04 × 10-7 |
| 6.23 |
1431 |
9.61 × 10-4 |
9.45 × 10-4 |
1.6 |
1.08 × 10-8 |
| 6.74 |
1494 |
9.66 × 10-4 |
8.98 × 10-4 |
7.0 |
4.56 × 10-8 |
| 7.16 |
1472 |
9.68 × 10-4 |
9.30 × 10-4 |
3.9 |
2.58 × 10-8 |
| 7.47 |
1472 |
9.71 × 10-4 |
7.87 × 10-4 |
19.0 |
1.25 × 10-7 |
| 8.19 |
1491 |
9.76 × 10-4 |
7.67 × 10-4 |
21.5 |
1.40 × 10-7 |
| 8.51 |
1482 |
9.73 × 10-4 |
7.71 × 10-4 |
20.8 |
1.37 × 10-7 |
| 8.88 |
1481 |
9.69 × 10-4 |
5.56 × 10-4 |
42.6 |
2.79 × 10-7 |
| 9.25 |
1462 |
9.63 × 10-4 |
3.29 × 10-4 |
65.8 |
4.34 × 10-7 |
| 10.02 |
1452 |
9.55 × 10-4 |
9.74 × 10-5 |
89.8 |
5.91 × 10-7 |
|
|
|||||
| Total Sr = 10-4 M, aged for 2 days |
± 5% |
||||
|
|
|||||
| 6.43 |
1570 |
1.09 × 10-4 |
1.16 × 10-4 |
-5.5 |
-3.85 × 10-9 |
| 6.78 |
1433 |
1.10 × 10-4 |
1.10 × 10-4 |
-0.6 |
-4.52 × 10-10 |
| 7.23 |
1431 |
1.10 × 10-4 |
1.13 × 10-4 |
-2.7 |
-2.09 × 10-9 |
| 7.49 |
1442 |
1.11 × 10-4 |
1.10 × 10-4 |
1.0 |
7.44 × 10-10 |
| 7.78 |
1602 |
1.11 × 10-4 |
1.00 × 10-4 |
9.6 |
6.63 × 10-9 |
| 8.19 |
1555 |
1.11 × 10-4 |
8.76 × 10-5 |
20.8 |
1.48 × 10-8 |
| 8.89 |
1511 |
1.10 × 10-4 |
4.53 × 10-5 |
58.7 |
4.26 × 10-8 |
| 9.38 |
1532 |
1.10 × 10-4 |
3.44 × 10-5 |
68.6 |
4.90 × 10-8 |
| 9.9 |
1540 |
1.09 × 10-4 |
1.88 × 10-5 |
82.7 |
5.85 × 10-8 |
|
|
|||||
| Total Sr = 10-5 M, aged for 2 days |
± 5% |
||||
|
|
|||||
| 6.43 |
1540 |
1.08 × 10-5 |
1.06 × 10-5 |
1.4 |
9.51 × 10-11 |
| 6.74 |
1534 |
1.08 × 10-5 |
1.05 × 10-5 |
3.1 |
2.19 × 10-10 |
| 7.30 |
1501 |
1.09 × 10-5 |
1.07 × 10-5 |
1.8 |
1.29 × 10-10 |
| 7.73 |
1423 |
1.09 × 10-5 |
9.67 × 10-6 |
11.2 |
8.54 × 10-10 |
| 8.05 |
1463 |
1.09 × 10-5 |
9.31 × 10-6 |
14.6 |
1.08 × 10-9 |
| 8.42 |
1503 |
1.09 × 10-5 |
7.79 × 10-6 |
28.4 |
2.05 × 10-9 |
| 9.22 |
1502 |
1.08 × 10-5 |
3.88 × 10-6 |
64.2 |
4.62 × 10-9 |
| 9.79 |
1481 |
1.08 × 10-5 |
1.61 × 10-6 |
85.0 |
6.19 × 10-9 |
| 10.21 |
1416 |
1.07 × 10-5 |
7.34 × 10-7 |
93.2 |
7.06 × 10-9 |
Carroll et al. Geochemical Transactions 2008 9:2 doi:10.1186/1467-4866-9-2 |
|||||