|
Solution analyses for strontium sorption to amorphous silica in air, I = 0.1 M NaCl and T = 25°C. |
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| Final pH |
Surface Area m2 L-1 |
Initial [Sr] M |
Final [Sr] M |
%Sr sorbed |
Γ Sr sorbed Mol m-2 |
Total Dissolved Carbonate M |
|
|
||||||
| Total Sr = 10-3 M aged for 2 days |
± 5% |
|||||
|
|
||||||
| 6.67 |
11073 |
9.98 × 10-4 |
1.01 × 10-3 |
-1.5 |
-1.31 × 10-9 |
not measured |
| 6.72 |
11098 |
1.00 × 10-3 |
1.02 × 10-3 |
-1.6 |
-1.43 × 10-9 |
not measured |
| 6.80 |
11086 |
9.98 × 10-4 |
1.03 × 10-3 |
-3.6 |
-3.27 × 10-9 |
not measured |
| 6.90 |
11060 |
9.94 × 10-4 |
1.02 × 10-3 |
-2.5 |
-2.21 × 10-9 |
not measured |
| 7.19 |
11012 |
9.91 × 10-4 |
1.05 × 10-3 |
-6.1 |
-5.46 × 10-9 |
not measured |
| 7.89 |
10724 |
9.66 × 10-4 |
9.35 × 10-4 |
3.2 |
2.89 × 10-9 |
not measured |
| 8.32 |
10522 |
9.45 × 10-4 |
8.00 × 10-4 |
15.4 |
1.38 × 10-8 |
not measured |
| 8.65 |
10237 |
9.23 × 10-4 |
5.28 × 10-4 |
42.7 |
3.85 × 10-8 |
not measured |
| 9.58 |
9224 |
8.33 × 10-4 |
3.22 × 10-5 |
96.1 |
8.68 × 10-8 |
not measured |
| 6.54 |
11016 |
1.00 × 10-3 |
1.02 × 10-3 |
-1.5 |
-1.36 × 10-9 |
1.72 × 10-5 |
| 6.61 |
11026 |
1.00 × 10-3 |
1.01 × 10-3 |
-0.4 |
-3.41 × 10-10 |
3.61 × 10-5 |
| 6.70 |
11004 |
9.97 × 10-4 |
1.01 × 10-3 |
-0.9 |
-8.38 × 10-10 |
3.34 × 10-5 |
| 6.73 |
11003 |
9.99 × 10-4 |
9.99 × 10-4 |
0.0 |
1.79 × 10-12 |
3.69 × 10-6 |
| 7.14 |
10961 |
9.93 × 10-4 |
9.69 × 10-4 |
2.4 |
2.19 × 10-9 |
2.67 × 10-5 |
| 7.72 |
10758 |
9.77 × 10-4 |
8.82 × 10-4 |
9.7 |
8.76 × 10-9 |
1.72 × 10-4 |
| 8.65 |
10327 |
9.36 × 10-4 |
5.85 × 10-4 |
37.5 |
3.40 × 10-8 |
3.52 × 10-4 |
| 8.98 |
10019 |
9.04 × 10-4 |
4.33 × 10-4 |
52.1 |
4.70 × 10-8 |
4.44 × 10-4 |
| 9.57 |
9565 |
8.65 × 10-4 |
2.20 × 10-4 |
74.6 |
6.75 × 10-8 |
5.64 × 10-4 |
| 7.98 |
10670 |
9.68 × 10-4 |
8.49 × 10-4 |
12.2 |
1.11 × 10-8 |
1.04 × 10-4 |
| 8.06 |
10590 |
9.68 × 10-4 |
8.60 × 10-4 |
11.1 |
1.01 × 10-8 |
8.95 × 10-5 |
| 8.82 |
10187 |
9.27 × 10-4 |
5.25 × 10-4 |
43.3 |
3.95 × 10-8 |
1.05 × 10-4 |
| 8.84 |
10272 |
9.27 × 10-4 |
5.05 × 10-4 |
45.5 |
4.11 × 10-8 |
1.54 × 10-4 |
| 8.85 |
10228 |
9.28 × 10-4 |
5.30 × 10-4 |
42.8 |
3.89 × 10-8 |
1.46 × 10-4 |
| 8.91 |
10160 |
9.27 × 10-4 |
5.14 × 10-4 |
44.6 |
4.07 × 10-8 |
2.13 × 10-4 |
| 9.16 |
9992 |
9.05 × 10-4 |
3.86 × 10-4 |
57.3 |
5.20 × 10-8 |
1.53 × 10-4 |
| 9.19 |
9967 |
9.06 × 10-4 |
3.91 × 10-4 |
56.8 |
5.17 × 10-8 |
1.52 × 10-4 |
| 9.26 |
9767 |
8.88 × 10-4 |
3.77 × 10-4 |
57.5 |
5.23 × 10-8 |
3.47 × 10-5 |
| 9.38 |
9961 |
9.00 × 10-4 |
3.40 × 10-4 |
62.2 |
5.62 × 10-8 |
2.40 × 10-5 |
| 9.44 |
9849 |
8.96 × 10-4 |
3.24 × 10-4 |
63.8 |
5.81 × 10-8 |
9.92 × 10-5 |
| 9.53 |
9822 |
8.88 × 10-4 |
2.83 × 10-4 |
68.2 |
6.16 × 10-8 |
7.95 × 10-5 |
| 9.54 |
9787 |
8.88 × 10-4 |
2.72 × 10-4 |
69.4 |
6.30 × 10-8 |
1.85 × 10-4 |
| 9.72 |
9461 |
8.58 × 10-4 |
2.29 × 10-4 |
73.3 |
6.65 × 10-8 |
1.82 × 10-4 |
|
|
||||||
| Total Sr = 10-4 M aged for 2 days |
± 5% |
|||||
|
|
||||||
| 7.08 |
11079 |
1.00 × 10-4 |
1.04 × 10-4 |
-3.5 |
-3.15 × 10-10 |
not measured |
| 6.41 |
11063 |
1.01 × 10-4 |
1.06 × 10-4 |
-5.1 |
-4.57 × 10-10 |
not measured |
| 6.92 |
11002 |
1.00 × 10-4 |
1.09 × 10-4 |
-8.9 |
-8.11 × 10-10 |
not measured |
| 7.02 |
10966 |
9.99 × 10-5 |
1.05 × 10-4 |
-5.3 |
-4.79 × 10-10 |
not measured |
| 7.26 |
10922 |
9.88 × 10-5 |
9.88 × 10-5 |
0.0 |
4.05 × 10-13 |
not measured |
| 7.50 |
10712 |
9.70 × 10-5 |
9.10 × 10-5 |
6.2 |
5.61 × 10-10 |
not measured |
| 8.57 |
10078 |
9.14 × 10-5 |
5.30 × 10-5 |
42.2 |
3.81 × 10-9 |
not measured |
| 9.33 |
9404 |
8.51 × 10-5 |
2.15 × 10-5 |
75.2 |
6.77 × 10-9 |
not measured |
| 9.86 |
8585 |
7.81 × 10-5 |
9.13 × 10-6 |
88.7 |
8.03 × 10-9 |
not measured |
|
|
||||||
| Total Sr = 10-5 M aged for 2 days |
± 5% |
|||||
|
|
||||||
| 6.21 |
10913 |
1.05 × 10-5 |
1.07 × 10-5 |
-1.4 |
-1.39 × 10-11 |
not measured |
| 6.40 |
11302 |
1.06 × 10-5 |
1.04 × 10-5 |
1.2 |
1.13 × 10-11 |
not measured |
| 6.70 |
11458 |
1.06 × 10-5 |
1.03 × 10-5 |
2.0 |
1.88 × 10-11 |
not measured |
| 7.15 |
11367 |
1.05 × 10-5 |
1.01 × 10-5 |
3.8 |
3.54 × 10-11 |
not measured |
| 6.95 |
10918 |
1.05 × 10-5 |
1.04 × 10-5 |
1.0 |
9.75 × 10-12 |
not measured |
| 7.60 |
10844 |
1.03 × 10-5 |
9.45 × 10-6 |
8.5 |
8.10 × 10-11 |
not measured |
| 7.91 |
10811 |
1.03 × 10-5 |
8.71 × 10-6 |
15.1 |
1.43 × 10-10 |
not measured |
| 8.92 |
10175 |
9.72 × 10-6 |
4.36 × 10-6 |
55.2 |
5.27 × 10-10 |
not measured |
| 9.58 |
9544 |
9.12 × 10-6 |
1.85 × 10-6 |
79.7 |
7.62 × 10-10 |
not measured |
|
|
||||||
| Total Sr = 10-6 M aged for 2 days |
± 10% |
|||||
|
|
||||||
| 6.52 |
11049 |
1.59 × 10-6 |
1.65 × 10-6 |
-3.9 |
-5.60 × 10-12 |
not measured |
| 6.64 |
11038 |
1.59 × 10-6 |
1.53 × 10-6 |
3.4 |
4.84 × 10-12 |
not measured |
| 6.71 |
11025 |
1.58 × 10-6 |
1.50 × 10-6 |
5.4 |
7.78 × 10-12 |
not measured |
| 6.81 |
11019 |
1.58 × 10-6 |
1.48 × 10-6 |
6.7 |
9.56 × 10-12 |
not measured |
| 6.88 |
11030 |
1.58 × 10-6 |
1.51 × 10-6 |
4.5 |
6.42 × 10-12 |
not measured |
| 7.62 |
10867 |
1.56 × 10-6 |
1.42 × 10-6 |
8.8 |
1.26 × 10-11 |
not measured |
| 8.39 |
10590 |
1.52 × 10-6 |
1.13 × 10-6 |
25.3 |
3.64 × 10-11 |
not measured |
| 9.06 |
10235 |
1.47 × 10-6 |
7.21 × 10-7 |
50.9 |
7.32 × 10-11 |
not measured |
| 9.59 |
9873 |
1.42 × 10-6 |
3.89 × 10-7 |
72.5 |
1.04 × 10-10 |
not measured |
|
|
||||||
| Total Sr = 7 × 10-7 M aged for 2 days |
± 20% |
|||||
|
|
||||||
| 6.89 |
11022 |
6.81 × 10-7 |
6.46 × 10-7 |
5.1 |
3.14 × 10-12 |
not measured |
| 6.50 |
11070 |
6.83 × 10-7 |
6.57 × 10-7 |
3.8 |
2.31 × 10-12 |
not measured |
| 6.70 |
11016 |
6.80 × 10-7 |
6.82 × 10-7 |
-0.3 |
-2.12 × 10-13 |
not measured |
| 6.43 |
11013 |
6.80 × 10-7 |
7.18 × 10-7 |
-5.6 |
-3.44 × 10-12 |
not measured |
| 7.56 |
10685 |
6.59 × 10-7 |
5.63 × 10-7 |
14.7 |
9.05 × 10-12 |
not measured |
| 7.73 |
10508 |
6.49 × 10-7 |
5.15 × 10-7 |
20.6 |
1.27 × 10-11 |
not measured |
| 8.52 |
9978 |
6.16 × 10-7 |
3.34 × 10-7 |
45.7 |
2.82 × 10-11 |
not measured |
| 9.05 |
9538 |
5.89 × 10-7 |
1.71 × 10-7 |
70.9 |
4.38 × 10-11 |
not measured |
| 9.53 |
8920 |
5.50 × 10-7 |
8.10 × 10-8 |
85.3 |
5.26 × 10-11 |
not measured |
Carroll et al. Geochemical Transactions 2008 9:2 doi:10.1186/1467-4866-9-2 |
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