|
Solution analyses for strontium sorption to amorphous silica in nitrogen atmosphere, I = 0.1 M NaCl and T = 25°C. |
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| Final pH |
Surface Area m2 L-1 |
Initial [Sr] M |
Final [Sr] M |
%Sr orbed |
Γ Sr sorbed Mol m-2 |
|
|
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| Total Sr = 10-3 M aged for 2 days |
± 5% |
||||
|
|
|||||
| 3.14 |
10934 |
9.99 × 10-4 |
9.71 × 10-4 |
2.8 |
2.57 × 10-9 |
| 3.89 |
10983 |
1.00 × 10-3 |
9.90 × 10-4 |
1.3 |
1.17 × 10-9 |
| 3.89 |
10983 |
1.00 × 10-3 |
9.88 × 10-4 |
1.5 |
1.38 × 10-9 |
| 5.42 |
11037 |
1.01 × 10-3 |
9.86 × 10-4 |
2.0 |
1.86 × 10-9 |
| 6.02 |
11075 |
1.01 × 10-3 |
9.83 × 10-4 |
2.5 |
2.32 × 10-9 |
| 6.33 |
11115 |
1.01 × 10-3 |
9.78 × 10-4 |
3.4 |
3.06 × 10-9 |
| 6.55 |
11095 |
1.01 × 10-3 |
9.97 × 10-4 |
1.5 |
1.40 × 10-9 |
| 7.12 |
11101 |
1.01 × 10-3 |
9.80 × 10-4 |
3.2 |
2.92 × 10-9 |
| 7.04 |
11035 |
1.01 × 10-3 |
9.74 × 10-4 |
3.4 |
3.15 × 10-9 |
| 7.42 |
10855 |
9.95 × 10-4 |
9.33 × 10-4 |
6.3 |
5.74 × 10-9 |
| 7.95 |
10705 |
9.80 × 10-4 |
8.40 × 10-4 |
14.2 |
1.30 × 10-8 |
| 8.62 |
10415 |
9.54 × 10-4 |
6.23 × 10-4 |
34.7 |
3.18 × 10-8 |
| 9.12 |
10088 |
9.21 × 10-4 |
4.16 × 10-4 |
54.8 |
5.00 × 10-8 |
| 9.52 |
9720 |
8.88 × 10-4 |
2.64 × 10-4 |
70.3 |
6.43 × 10-8 |
|
|
|||||
| Total Sr = 10-4 M aged for 2 days |
± 5% |
||||
|
|
|||||
| 4.20 |
11019 |
1.00 × 10-4 |
9.85 × 10-5 |
2.0 |
1.80 × 10-10 |
| 4.89 |
11005 |
1.01 × 10-4 |
9.88 × 10-5 |
1.7 |
1.60 × 10-10 |
| 5.50 |
11034 |
1.01 × 10-4 |
9.92 × 10-5 |
1.6 |
1.42 × 10-10 |
| 6.22 |
11013 |
1.01 × 10-4 |
1.01 × 10-4 |
0.4 |
3.93 × 10-11 |
| 6.33 |
11057 |
1.01 × 10-4 |
1.01 × 10-4 |
0.5 |
4.92 × 10-11 |
| 6.71 |
11110 |
1.01 × 10-4 |
9.97 × 10-5 |
1.7 |
1.56 × 10-10 |
| 6.62 |
11087 |
1.01 × 10-4 |
1.01 × 10-4 |
0.7 |
6.64 × 10-11 |
| 7.01 |
11086 |
1.01 × 10-4 |
9.84 × 10-5 |
2.5 |
2.30 × 10-10 |
| 7.46 |
10912 |
9.96 × 10-5 |
9.38 × 10-5 |
5.8 |
5.31 × 10-10 |
| 7.82 |
10809 |
9.86 × 10-5 |
8.75 × 10-5 |
11.3 |
1.03 × 10-9 |
| 8.54 |
10475 |
9.56 × 10-5 |
6.42 × 10-5 |
32.8 |
2.99 × 10-9 |
| 8.95 |
10257 |
9.39 × 10-5 |
4.89 × 10-5 |
47.9 |
4.38 × 10-9 |
| 9.43 |
9888 |
9.05 × 10-5 |
2.84 × 10-5 |
68.7 |
6.29 × 10-9 |
|
|
|||||
| Total Sr = 10-5 M aged for 2 days |
± 5% |
||||
|
|
|||||
| 6.82 |
11081 |
1.06 × 10-5 |
1.06 × 10-5 |
-0.5 |
-4.60 × 10-12 |
| 6.57 |
11086 |
1.06 × 10-5 |
1.04 × 10-5 |
1.5 |
1.41 × 10-11 |
| 6.57 |
11044 |
1.06 × 10-5 |
9.30 × 10-6 |
12.1 |
1.15 × 10-10 |
| 6.84 |
10939 |
1.05 × 10-5 |
1.03 × 10-5 |
1.5 |
1.42 × 10-11 |
| 7.22 |
10842 |
1.04 × 10-5 |
9.47 × 10-6 |
8.6 |
8.19 × 10-11 |
| 7.88 |
10672 |
1.02 × 10-5 |
8.33 × 10-6 |
18.3 |
1.74 × 10-10 |
| 7.91 |
10481 |
1.00 × 10-5 |
7.53 × 10-6 |
24.7 |
2.35 × 10-10 |
| 9.16 |
9584 |
9.14 × 10-6 |
2.40 × 10-6 |
73.8 |
7.03 × 10-10 |
| 9.74 |
8484 |
8.13 × 10-6 |
8.33 × 10-7 |
89.8 |
8.60 × 10-10 |
|
|
|||||
| Total Sr = 1.5 10-6 M aged for 2 days |
± 10% |
||||
|
|
|||||
| 6.32 |
11056 |
1.51 × 10-6 |
1.60 × 10-6 |
-5.5 |
-7.55 × 10-12 |
| 6.53 |
11013 |
1.51 × 10-6 |
1.56 × 10-6 |
-3.4 |
-4.65 × 10-12 |
| 6.82 |
11000 |
1.51 × 10-6 |
1.59 × 10-6 |
-5.0 |
-6.85 × 10-12 |
| 6.83 |
11032 |
1.51 × 10-6 |
1.55 × 10-6 |
-2.8 |
-3.86 × 10-12 |
| 7.06 |
10988 |
1.50 × 10-6 |
1.39 × 10-6 |
7.3 |
9.99 × 10-12 |
| 7.29 |
10900 |
1.49 × 10-6 |
1.45 × 10-6 |
2.7 |
3.74 × 10-12 |
| 8.65 |
9964 |
1.37 × 10-6 |
6.96 × 10-7 |
49.1 |
6.74 × 10-11 |
| 9.10 |
9534 |
1.31 × 10-6 |
3.77 × 10-7 |
71.2 |
9.76 × 10-11 |
| 9.16 |
9562 |
1.31 × 10-6 |
3.65 × 10-7 |
72.1 |
9.87 × 10-11 |
| 6.62 |
11041 |
1.52 × 10-6 |
1.51 × 10-6 |
0.6 |
7.93 × 10-13 |
| 6.59 |
11092 |
1.52 × 10-6 |
1.51 × 10-6 |
0.6 |
7.89 × 10-13 |
| 6.52 |
11036 |
1.52 × 10-6 |
1.48 × 10-6 |
2.7 |
3.71 × 10-12 |
| 6.77 |
10957 |
1.51 × 10-6 |
1.59 × 10-6 |
-5.6 |
-7.65 × 10-12 |
| 7.30 |
10831 |
1.48 × 10-6 |
1.37 × 10-6 |
7.4 |
1.01 × 10-11 |
| 9.62 |
9014 |
1.24 × 10-6 |
1.26 × 10-7 |
89.8 |
1.23 × 10-10 |
|
|
|||||
| Total Sr = 6 × 10 -7 M aged for 2 days |
± 20% |
||||
|
|
|||||
| 6.34 |
11073 |
6.10 × 10-7 |
6.91 × 10-7 |
-13.3 |
-7.33 × 10-12 |
| 6.65 |
11058 |
6.09 × 10-7 |
6.70 × 10-7 |
-10.0 |
-5.53 × 10-12 |
| 6.78 |
11046 |
6.08 × 10-7 |
6.41 × 10-7 |
-5.4 |
-2.99 × 10-12 |
| 6.83 |
11028 |
6.07 × 10-7 |
6.20 × 10-7 |
-2.1 |
-1.13 × 10-12 |
| 7.29 |
10862 |
5.98 × 10-7 |
6.01 × 10-7 |
-0.6 |
-3.08 × 10-13 |
| 7.2 |
10841 |
5.97 × 10-7 |
6.20 × 10-7 |
-3.8 |
-2.07 × 10-12 |
| 8.66 |
9955 |
5.48 × 10-7 |
2.50 × 10-7 |
54.4 |
3.00 × 10-11 |
| 9.06 |
9417 |
5.19 × 10-7 |
1.21 × 10-7 |
76.7 |
4.22 × 10-11 |
| 9.62 |
8977 |
4.94 × 10-7 |
4.34 × 10-8 |
91.2 |
5.02 × 10-11 |
Carroll et al. Geochemical Transactions 2008 9:2 doi:10.1186/1467-4866-9-2 |
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