Table 1

Solution analyses for strontium sorption to amorphous silica in nitrogen atmosphere, I = 0.1 M NaCl and T = 25°C.

Final pH
Surface Area m2 L-1
Initial [Sr] M
Final [Sr] M
%Sr orbed
Γ Sr sorbed Mol m-2

Total Sr = 10-3 M aged for 2 days

± 5%


3.14
10934
9.99 × 10-4
9.71 × 10-4
2.8
2.57 × 10-9
3.89
10983
1.00 × 10-3
9.90 × 10-4
1.3
1.17 × 10-9
3.89
10983
1.00 × 10-3
9.88 × 10-4
1.5
1.38 × 10-9
5.42
11037
1.01 × 10-3
9.86 × 10-4
2.0
1.86 × 10-9
6.02
11075
1.01 × 10-3
9.83 × 10-4
2.5
2.32 × 10-9
6.33
11115
1.01 × 10-3
9.78 × 10-4
3.4
3.06 × 10-9
6.55
11095
1.01 × 10-3
9.97 × 10-4
1.5
1.40 × 10-9
7.12
11101
1.01 × 10-3
9.80 × 10-4
3.2
2.92 × 10-9
7.04
11035
1.01 × 10-3
9.74 × 10-4
3.4
3.15 × 10-9
7.42
10855
9.95 × 10-4
9.33 × 10-4
6.3
5.74 × 10-9
7.95
10705
9.80 × 10-4
8.40 × 10-4
14.2
1.30 × 10-8
8.62
10415
9.54 × 10-4
6.23 × 10-4
34.7
3.18 × 10-8
9.12
10088
9.21 × 10-4
4.16 × 10-4
54.8
5.00 × 10-8
9.52
9720
8.88 × 10-4
2.64 × 10-4
70.3
6.43 × 10-8

Total Sr = 10-4 M aged for 2 days

± 5%


4.20
11019
1.00 × 10-4
9.85 × 10-5
2.0
1.80 × 10-10
4.89
11005
1.01 × 10-4
9.88 × 10-5
1.7
1.60 × 10-10
5.50
11034
1.01 × 10-4
9.92 × 10-5
1.6
1.42 × 10-10
6.22
11013
1.01 × 10-4
1.01 × 10-4
0.4
3.93 × 10-11
6.33
11057
1.01 × 10-4
1.01 × 10-4
0.5
4.92 × 10-11
6.71
11110
1.01 × 10-4
9.97 × 10-5
1.7
1.56 × 10-10
6.62
11087
1.01 × 10-4
1.01 × 10-4
0.7
6.64 × 10-11
7.01
11086
1.01 × 10-4
9.84 × 10-5
2.5
2.30 × 10-10
7.46
10912
9.96 × 10-5
9.38 × 10-5
5.8
5.31 × 10-10
7.82
10809
9.86 × 10-5
8.75 × 10-5
11.3
1.03 × 10-9
8.54
10475
9.56 × 10-5
6.42 × 10-5
32.8
2.99 × 10-9
8.95
10257
9.39 × 10-5
4.89 × 10-5
47.9
4.38 × 10-9
9.43
9888
9.05 × 10-5
2.84 × 10-5
68.7
6.29 × 10-9

Total Sr = 10-5 M aged for 2 days

± 5%


6.82
11081
1.06 × 10-5
1.06 × 10-5
-0.5
-4.60 × 10-12
6.57
11086
1.06 × 10-5
1.04 × 10-5
1.5
1.41 × 10-11
6.57
11044
1.06 × 10-5
9.30 × 10-6
12.1
1.15 × 10-10
6.84
10939
1.05 × 10-5
1.03 × 10-5
1.5
1.42 × 10-11
7.22
10842
1.04 × 10-5
9.47 × 10-6
8.6
8.19 × 10-11
7.88
10672
1.02 × 10-5
8.33 × 10-6
18.3
1.74 × 10-10
7.91
10481
1.00 × 10-5
7.53 × 10-6
24.7
2.35 × 10-10
9.16
9584
9.14 × 10-6
2.40 × 10-6
73.8
7.03 × 10-10
9.74
8484
8.13 × 10-6
8.33 × 10-7
89.8
8.60 × 10-10

Total Sr = 1.5 10-6 M aged for 2 days

± 10%


6.32
11056
1.51 × 10-6
1.60 × 10-6
-5.5
-7.55 × 10-12
6.53
11013
1.51 × 10-6
1.56 × 10-6
-3.4
-4.65 × 10-12
6.82
11000
1.51 × 10-6
1.59 × 10-6
-5.0
-6.85 × 10-12
6.83
11032
1.51 × 10-6
1.55 × 10-6
-2.8
-3.86 × 10-12
7.06
10988
1.50 × 10-6
1.39 × 10-6
7.3
9.99 × 10-12
7.29
10900
1.49 × 10-6
1.45 × 10-6
2.7
3.74 × 10-12
8.65
9964
1.37 × 10-6
6.96 × 10-7
49.1
6.74 × 10-11
9.10
9534
1.31 × 10-6
3.77 × 10-7
71.2
9.76 × 10-11
9.16
9562
1.31 × 10-6
3.65 × 10-7
72.1
9.87 × 10-11
6.62
11041
1.52 × 10-6
1.51 × 10-6
0.6
7.93 × 10-13
6.59
11092
1.52 × 10-6
1.51 × 10-6
0.6
7.89 × 10-13
6.52
11036
1.52 × 10-6
1.48 × 10-6
2.7
3.71 × 10-12
6.77
10957
1.51 × 10-6
1.59 × 10-6
-5.6
-7.65 × 10-12
7.30
10831
1.48 × 10-6
1.37 × 10-6
7.4
1.01 × 10-11
9.62
9014
1.24 × 10-6
1.26 × 10-7
89.8
1.23 × 10-10

Total Sr = 6 × 10 -7 M aged for 2 days

± 20%


6.34
11073
6.10 × 10-7
6.91 × 10-7
-13.3
-7.33 × 10-12
6.65
11058
6.09 × 10-7
6.70 × 10-7
-10.0
-5.53 × 10-12
6.78
11046
6.08 × 10-7
6.41 × 10-7
-5.4
-2.99 × 10-12
6.83
11028
6.07 × 10-7
6.20 × 10-7
-2.1
-1.13 × 10-12
7.29
10862
5.98 × 10-7
6.01 × 10-7
-0.6
-3.08 × 10-13
7.2
10841
5.97 × 10-7
6.20 × 10-7
-3.8
-2.07 × 10-12
8.66
9955
5.48 × 10-7
2.50 × 10-7
54.4
3.00 × 10-11
9.06
9417
5.19 × 10-7
1.21 × 10-7
76.7
4.22 × 10-11
9.62
8977
4.94 × 10-7
4.34 × 10-8
91.2
5.02 × 10-11

Carroll et al. Geochemical Transactions 2008 9:2   doi:10.1186/1467-4866-9-2