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Sequential chemical extraction procedure |
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| Form of selenium |
Extraction method |
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| Water-leachable |
A 3-g sample of coal was transferred into a container. Add 20 mL of Milli-Q water at room temperature. Let it stand for 24 h. The suspension was then centrifuged at 3500 rpm for 20 min. |
| Ion-exchangeable |
20 mL of ammonium acetate (1 N) was added to the dried residual solids at room temperature for 24 h, suspension was then centrifuged at 3500 rpm for 20 min. |
| Organic matter-bound |
The dried residual solid was treated with CHCl3 (1.47 g/cm3). After 24 h of stirring at room temperature, a float-sink separation was performed by centrifugation (3500 rpm for 20 min). The float fraction (1.47 g/cm3) of the sample was dried at 40°C, then treated with 12 mL of an oxidizing mixture (HNO3: HCl = 3:1) and 3 mL HF in a Telfon beaker which was put in a microwave oven (at 600 W for 30 min; at 1200 W for 25 min; and at 1200 W for 30 min). |
| Carbonate-bound |
The sink fraction (1.47 g/cm3) was dried at 40°C, and then treated with 20 ml HCl (0.5%). The suspension was then centrifuged at 3500 rpm for 20 min. |
| Silicate-bound |
The dried residual solid was treated with CHBr3 (2.89 g/cm3). After 24 h stirring at room temperature, a float-sink separation was performed by high-speed centrifugation (5000 rpm for 20 min). The float fraction (2.89 g/cm3) of the sample was dried at 40°C, and then treated with 12 mL of an oxidizing mixture (HNO3: HCl = 3:1) and 3 mL HF in a Telfon beaker which ws put in a microwave oven (at 600 W for 30 min; at 1200 W for 25 min; and at 1200 W for 30 min). |
| Sulfide-bound |
The sink fraction (2.89 g/cm3) was dried at 40°C, and then treated with an oxidizing mixture (HNO3: HCl = 3:1) and HF in a Telfon which was put in a microwave oven (at 600 W for 30 min; at 1200 W for 25 min; and at 1200 W for 30 min). |
Zhang et al. Geochemical Transactions 2007 8:14 doi:10.1186/1467-4866-8-14 |
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